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Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site

Received: 22 October 2014     Accepted: 31 October 2014     Published: 10 November 2014
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Abstract

In Japan, three deaths were reported at an inert solid waste landfill site after exposure to hydrogen sulfide (H2S) generated at the site. H2S gas is produced when sulfate-reducing bacteria (SRB) convert sulfate derived from waste gypsum board under anaerobic conditions. The recommended countermeasure is to supply oxygen by installing gas venting pipes. However, a large cost is necessary for pipe installation and the pipes are not applicable to coastal landfill sites. On the other hand, H2S generation suppression by nitrate (NO3) addition has been reported in sewage systems. In this study, in order to develop a method to suppress H2S generation by NO3 addition at a landfill site, the extent of suppression was quantitatively estimated. When NO3 reagent was added at the rate of 0.46 mmol-NO3/(L•d) into a liquid from which H2S gas was generated at the rate of 0.21 ± 0.05 mmol-H2S/(L•d), H2S generation rate was decreased to approximately 1/4 of the original rate. Although it was difficult to maintain the concentration of NO3 because it tended to disappear rapidly, the frequent addition of NO3 reagent to maintain the concentration of approximately 430 mg-NO3/L enabled us to control H2S concentration to below 1000 ppmv for one month and H2S generation rate to below 1/20 of the original rate.

Published in American Journal of Environmental Protection (Volume 3, Issue 5)
DOI 10.11648/j.ajep.20140305.20
Page(s) 267-274
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Landfill Site, Waste Gypsum Board, Hydrogen Sulfide, Generation Suppression, Nitrate

References
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Cite This Article
  • APA Style

    Shumpei Kitazaki, Kai Xiao, Kei Nakagawa, Tomonori Kindaichi, Hiroshi Asakura. (2014). Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site. American Journal of Environmental Protection, 3(5), 267-274. https://doi.org/10.11648/j.ajep.20140305.20

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    ACS Style

    Shumpei Kitazaki; Kai Xiao; Kei Nakagawa; Tomonori Kindaichi; Hiroshi Asakura. Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site. Am. J. Environ. Prot. 2014, 3(5), 267-274. doi: 10.11648/j.ajep.20140305.20

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    AMA Style

    Shumpei Kitazaki, Kai Xiao, Kei Nakagawa, Tomonori Kindaichi, Hiroshi Asakura. Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site. Am J Environ Prot. 2014;3(5):267-274. doi: 10.11648/j.ajep.20140305.20

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  • @article{10.11648/j.ajep.20140305.20,
      author = {Shumpei Kitazaki and Kai Xiao and Kei Nakagawa and Tomonori Kindaichi and Hiroshi Asakura},
      title = {Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site},
      journal = {American Journal of Environmental Protection},
      volume = {3},
      number = {5},
      pages = {267-274},
      doi = {10.11648/j.ajep.20140305.20},
      url = {https://doi.org/10.11648/j.ajep.20140305.20},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajep.20140305.20},
      abstract = {In Japan, three deaths were reported at an inert solid waste landfill site after exposure to hydrogen sulfide (H2S) generated at the site. H2S gas is produced when sulfate-reducing bacteria (SRB) convert sulfate derived from waste gypsum board under anaerobic conditions. The recommended countermeasure is to supply oxygen by installing gas venting pipes. However, a large cost is necessary for pipe installation and the pipes are not applicable to coastal landfill sites. On the other hand, H2S generation suppression by nitrate (NO3) addition has been reported in sewage systems. In this study, in order to develop a method to suppress H2S generation by NO3 addition at a landfill site, the extent of suppression was quantitatively estimated. When NO3 reagent was added at the rate of 0.46 mmol-NO3/(L•d) into a liquid from which H2S gas was generated at the rate of 0.21 ± 0.05 mmol-H2S/(L•d), H2S generation rate was decreased to approximately 1/4 of the original rate. Although it was difficult to maintain the concentration of NO3 because it tended to disappear rapidly, the frequent addition of NO3 reagent to maintain the concentration of approximately 430 mg-NO3/L enabled us to control H2S concentration to below 1000 ppmv for one month and H2S generation rate to below 1/20 of the original rate.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Hydrogen Sulfide Generation Suppression by Nitrate Addition – Application to Solid Waste Landfill Site
    AU  - Shumpei Kitazaki
    AU  - Kai Xiao
    AU  - Kei Nakagawa
    AU  - Tomonori Kindaichi
    AU  - Hiroshi Asakura
    Y1  - 2014/11/10
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ajep.20140305.20
    DO  - 10.11648/j.ajep.20140305.20
    T2  - American Journal of Environmental Protection
    JF  - American Journal of Environmental Protection
    JO  - American Journal of Environmental Protection
    SP  - 267
    EP  - 274
    PB  - Science Publishing Group
    SN  - 2328-5699
    UR  - https://doi.org/10.11648/j.ajep.20140305.20
    AB  - In Japan, three deaths were reported at an inert solid waste landfill site after exposure to hydrogen sulfide (H2S) generated at the site. H2S gas is produced when sulfate-reducing bacteria (SRB) convert sulfate derived from waste gypsum board under anaerobic conditions. The recommended countermeasure is to supply oxygen by installing gas venting pipes. However, a large cost is necessary for pipe installation and the pipes are not applicable to coastal landfill sites. On the other hand, H2S generation suppression by nitrate (NO3) addition has been reported in sewage systems. In this study, in order to develop a method to suppress H2S generation by NO3 addition at a landfill site, the extent of suppression was quantitatively estimated. When NO3 reagent was added at the rate of 0.46 mmol-NO3/(L•d) into a liquid from which H2S gas was generated at the rate of 0.21 ± 0.05 mmol-H2S/(L•d), H2S generation rate was decreased to approximately 1/4 of the original rate. Although it was difficult to maintain the concentration of NO3 because it tended to disappear rapidly, the frequent addition of NO3 reagent to maintain the concentration of approximately 430 mg-NO3/L enabled us to control H2S concentration to below 1000 ppmv for one month and H2S generation rate to below 1/20 of the original rate.
    VL  - 3
    IS  - 5
    ER  - 

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Author Information
  • Graduate School of Fisheries Science and Environmental Studies, Nagasaki University, Nagasaki, Japan

  • Graduate School of Fisheries Science and Environmental Studies, Nagasaki University, Nagasaki, Japan

  • Graduate School of Fisheries Science and Environmental Studies, Nagasaki University, Nagasaki, Japan

  • Department of Civil and Environmental Engineering, Hiroshima University, Hiroshima, Japan

  • Graduate School of Fisheries Science and Environmental Studies, Nagasaki University, Nagasaki, Japan

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